OPTICAL ROTATION OF HELICAL POLYMERS - PERIODIC BOUNDARY CONDITIONS

被引：57

作者：

LOXSOM, FM

机构：

[1] Institute of Molecular Biophysics, Department of Chemistry, Florida State University, Tallahassee

[2] Biophysics Dept., Michigan State Univ., E. Lansing, MI

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 11期

关键词：

D O I：

10.1063/1.1671881

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A general expression for the optical rotation of large helical polymers is developed. The assumption of periodic boundary conditions is shown to be valid. A major term in the optical rotation is found to be a direct result of the helical symmetry as reflected in the correct dipole selection rules.

引用

页码：4899 / &

共 15 条

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ANDO, T
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MOFFITT, W
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MOFFITT, W
YANG, JT
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1956, 42 (09) : 596 - 603
[9] THE OPTICAL ROTATORY DISPERSION OF SIMPLE POLYPEPTIDES .2.
MOFFITT, W
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1956, 42 (10) : 736 - 746
[10] SYMMETRY OF HELICAL POLYMERS - ELECTRONIC STATES OF DOUBLE-STRANDED POLYNUCLEOTIDES
RHODES, W
[J]. JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (10) : 2433 - &

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