PURE ROTATIONAL SPECTRUM OF BF3 IN ITS VIBRONIC GROUND-STATE

被引：5

作者：

KOPPEL, H ^{[1
]}

COULSON, CA ^{[1
]}

机构：

[1] DEPT THEORET CHEM,OXFORD,ENGLAND

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1979年 / 75卷 / 01期

关键词：

D O I：

10.1016/0022-2852(79)90147-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The centrifugally induced pure rotational absorption spectrum of BF3 in its vibronic ground state has been computed using the theory of Watson. Maximum absorption of order 10-5 (mol/liter)-1 cm-1 is found to occur in a frequency region around ∼30 cm-1. Due to the coincidence of the Q and R branches the full spectrum exhibits an intensity alternation of the individual lines which is not present in the case of Td molecules studied previously; it could facilitate the experimental detection of the spectrum. © 1979.

引用

页码：64 / 69

页数：6

共 32 条

[1]

Aliev M. R., 1973, Optics and Spectroscopy, V35, P147

[2]

ALIEV MR, 1971, JETP LETT-USSR, V14, P417

[3] BORON TRIFLUORIDE - ANALYSIS OF 2NU3 AND DETERMINATION OF XI33 [J].