ENAMINOSULFONIUM SALTS .3. MORPHOLINO GROUP AS STEREOINDICATOR IN AMINOBICYCLO[4.1.0]HEPTANES

被引：37

作者：

VILSMAIER, E

TROGER, W

机构：

[1] Fachbereich Chemie der Universität, Kaiserslautern, D-6750, Paul-Ehrlich-Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 10期

关键词：

D O I：

10.1002/anie.197907981

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

exo/endo‐Assignment of aminobicyclo[4.1.0]heptanes (particularly with two bridging substituents) can be accomplished by means of the 1H‐NMR spectrum of the morpholino derivatives 1 and 2 (ABXY and AA′XX′ pattern of morpholine protons). The sequence below illustrates the new entry to these bicyclic species (X=morpholino, OH, OCH3; YOH, OCH3). (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：798 / 800

页数：3

共 10 条

[1] CONJUGATED ENAMINES .3. SPECTROSCOPIC STRUCTURAL STUDIES OF CIS-FIXED, CYCLIC BETA ENAMINOESTERS WITH PARTICULAR CONSIDERATION OF INTERNAL HYDROGEN BRIDGES
BLAZEJEWSKI, JC
CANTACUZENE, D
WAKSELMAN, C
[J]. TETRAHEDRON, 1973, 29 (24) : 4233 - 4239
[2] CAM PL, 1971, CHEM SCR, V1, P65
[3] CANTACUZENE D, 1971, TETRAHEDRON LETT, P4807
[4] RING INVERSION IN MORPHOLINE AND PIPERAZINE DERIVATIVES STUDIED BY NUCLEAR MAGNETIC RESONANCE
HARRIS, RK
SPRAGG, RA
[J]. CHEMICAL COMMUNICATIONS, 1966, (10) : 314 - &
[5] SMUSZKOWICZ J, 1969, TETRAHEDRON LETT, P1309
[6] NUCLEAR MAGNETIC RESONANCE STUDIES OF 6-MEMBERED RINGS .2. CHEMICAL SHIFTS AND COUPLING CONSTANTS IN MORPHOLINE AND PIPERAZINE DERIVATIVES
SPRAGG, RA
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1968, (10): : 1128 - &
[7] SZMUSZKOVICZ J, 1967, TETRAHEDRON LETT, P3969
[8] SYNTHESIS AND THERMOLYSIS OF 2-AMINO-1-CYCLOALKENYLSULFONIUM SALTS
VILSMAIER, E
TROGER, W
SPRUGEL, W
GAGEL, K
[J]. CHEMISCHE BERICHTE-RECUEIL, 1979, 112 (08): : 2997 - 3006
[9] WASSERMAN HH, 1976, J ORG CHEM, V41, P153, DOI 10.1021/jo00863a038
[10] WASSERMAN HH, 1971, TETRAHEDRON LETT, P3721

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