INVESTIGATION OF THE HYDROLYSIS OF [SN(CH3)3(H2O)2]+ IN AQUEOUS-SOLUTION BY SN-119 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY

被引：17

作者：

HYNES, MJ

KEELY, JM

MCMANUS, J

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 12期

关键词：

D O I：

10.1039/dt9910003427

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrolysis of [Sn(CH3)3(H2O)2]+ has been investigated using Sn-119 NMR spectroscopy in aqueous solution at 25-degrees-C and ionic strength 0.5 mol dm-3. The ionic strength was adjusted using KCl, KNO3 or NaClO4. The chemical-shift data were processed using the computer program EQNMR to yield the stability constants and the chemical shifts of the various species present in solution. The results are compared with literature data obtained using other techniques.

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页码：3427 / 3429

页数：3

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