SPECTROSCOPIC INVESTIGATION OF VARIOUS PHOSPHORUS-SULFUR BONDS

被引：28

作者：

GOUBEAU, J

机构：

[1] Institut für anorganische Chemie, Universität Stuttgart

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1969年 / 8卷 / 05期

关键词：

Bond theory; Phosphorus–sulfur compounds;

D O I：

10.1002/anie.196903281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The results of spectroscopic investigations on phosphorus‐sulfur compounds, and particularly the force constants, reveal several factors that decisively influence the bonding. The effects of hybridization, the other bonding partners and their electronegativities, the π‐bonding components, and the ionic charge are discussed. It is shown that the PS bond, unlike the PO bond, never attains full double bond character, despite its great variability. Copyright © 1969 by Verlag Chemie, GmbH, Germany

引用

页码：328 / &

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