PARTIALLY RACEMIC COMPOUNDS AS BRUSHTAIL POSSUM URINARY METABOLITES

被引：46

作者：

CARMAN, RM

KLIKA, KD

机构：

[1] Department of Chemistry University of Queensland, Queensland

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1992年 / 45卷 / 04期

关键词：

D O I：

10.1071/CH9920651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydroxycineole (2) and cineolic acid (3) obtained as urinary metabolites from the brushtail possum (Trichosurus vulpecula) after the ingestion of 1,8-cineole (1), are partial racemates. The compounds have been examined by gas chromatographic analysis over chiral stationary phases, and by the synthesis of optically pure enantiomers. Female possums show different enantiomeric ratios from males. Possible advantages to the animal in the use of a partial racemate as a pheromone are discussed.

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页码：651 / 657

页数：7

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