RHODIUM-CATALYZED REACTION OF N,N-ACETALS WITH A HYDROSILANE AND CARBON-MONOXIDE

被引：20

作者：

IKEDA, S ^{[1
]}

CHATANI, N ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 11期

关键词：

D O I：

10.1021/om00059a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of [RhCl(CO)2]2, the reaction of N,N-acetals with a hydrosilane and carbon monoxide (140-degrees-C, 50 atm of CO) resulted in incorporation of CO with cleavage of one of the carbon-nitrogen bonds in the substrate. The structure of the products was highly dependent on the structure of the N,N-acetals.

引用

页码：3494 / 3495

页数：2

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