STRUCTURAL-PROPERTIES OF THE TI1-XNBXS2 PHASE

被引：8

作者：

FURUSETH, S

机构：

[1] Department of Chemistry, University of Oslo

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1992年 / 178卷

关键词：

D O I：

10.1016/0925-8388(92)90263-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Ti1-xNbxS2 phase crystallizing with the CdI2 (1T) type of structure has been investigated. At 1000-degrees-C and with a sulphur pressure of 6-8 atm the range of homogeneity is given by 0 < x < 0.98. The structural z parameter increases from the previously known value of 0.2501 in TiS2, through 0.2559 for x = 0.50 to 0.2611 for x = 0.95. The trigonal distortion of the metallic coordination polyhedron increases strongly and the interlayer distance of the structure decreases as titanium is substituted by the electron-richer niobium.

引用

页码：211 / 215

页数：5

共 12 条

[1] STRUCTURE REFINEMENT OF STOICHIOMETRIC TIS2 [J].