THE REACTION OF DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHANE)RUTHENIUM(II) WITH METHYL ACRYLATE - CRYSTAL-STRUCTURE OF BIS(METHYLACRYLATE)BIS(TRIPHENYLPHOSPHANE)(AQUA)RUTHENIUM(0)

被引：11

作者：

SUSTMANN, R ^{[1
]}

PATZKE, B ^{[1
]}

BOESE, R ^{[1
]}

机构：

[1] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,D-45117 ESSEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 470卷 / 1-2期

关键词：

RUTHENIUM; METHYL ACRYLATE; CRYSTAL STRUCTURE; X-RAY DIFFRACTION;

D O I：

10.1016/0022-328X(94)80167-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex H2Ru(PPh3)4 reacts with methyl acrylate to give bis(methylacrylate)bis(triphenylphosphane)ruthenium(0). Temperature-dependent NMR spectra show that the complex exists in two isomeric forms in solution. The major form (ca. 74%) has one methyl acrylate ligand eta4-coordinated and the other eta4-coordinated as a 1-oxabutadiene ligand. This complex reacts with water to give the monoaqua adduct, the crystal structure of which is reported.

引用

页码：191 / 197

页数：7

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