PERHALOALKYL HYPOCHLORITES AND PENTAFLUOROSULFUR HYPOCHLORITE .I. PREPARATION AND PROPERTIES

被引:68
作者
GOULD, DE
ANDERSON, LR
YOUNG, DE
FOX, WB
机构
[1] Industrial Chemicals Division Research Laboratory, Allied Chemical Corporation, Morristown
关键词
D O I
10.1021/ja01034a008
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation and properties of the new hypochlorites CF3OCl, C2F5OCl, i-C3F7OCl, CF2ClCF-(CF3)OCl, ClO(CF2)5OCl, and SF5OCl are described. The first five are most conveniently prepared through the cesium fluoride catalyzed addition of chlorine monofluoride to the appropriate carbonyl compound at low temperature. Pentafluorosulfur hypochlorite is prepared through an analogous reaction in which F4SO is used rather than a carbonyl compound. The new perhaloalkyl hypochlorites appear to be much more stable than the corresponding primary and secondary alkyl hypochlorites. © 1969, American Chemical Society. All rights reserved.
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页码:1310 / &
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