FREE-RADICAL REACTIONS OF FLUOROALKANESULFENYL HALIDES .3. REACTIONS OF FLUOROALKANESULFENYL AND CHLOROFLUOROALKANESULFENYL CHLORIDES WITH HYDROCARBONS

被引：9

作者：

HARRIS, JF

机构：

[1] Central Research and Development Department, Experimental Station, E. I. du Pont de Nemours and Company, Delaware 19898, Wilmington

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 04期

关键词：

D O I：

10.1021/jo01318a018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Free-radical reactions of several fluoroalkane- and chlorofluoroalkanesulfenyl chlorides with toluene, cyclohexane, and butane have been studied. The organic products obtained from these reactions include thiols, disulfides, sulfides, and chlorohydrocarbons. The relative yields of these products depend upon the structure of both the sulfenyl chloride and the hydrocarbon. Steric arguments are proposed to account for the results. © 1979, American Chemical Society. All rights reserved.

引用

页码：563 / 569

页数：7

共 20 条

[1] Andreades S., 1963, Patent No. [US3081350, 3081350]
[2] ORGANOMETALLIC AND METALLOID COMPOUNDS MADE FROM HEPTAFLUORO-2-IODOPROPANE, AND THEIR PROPERTIES
CHAMBERS, RD
MUSGRAVE, WK
SAVORY, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1962, (MAY): : 1993 - &
[3] REACTIONS OF PERFLUOROALKYLCARBANIONS WITH SULFUR
DYATKIN, BL
STERLIN, SR
ZHURAVKO.LG
MARTYNOV, BI
MYSOV, EI
KNUNYANT.IL
[J]. TETRAHEDRON, 1973, 29 (18) : 2759 - 2767
[4] FREE-RADICAL ADDITION OF TRIFLUOROMETHANESULFENYL CHLORIDE TO HALOOLEFINS
HARRIS, JF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (16) : 3148 - &
[5] FREE RADICAL ADDITION OF HYDROGEN SULFIDE TO FLUOROETHYLENES
HARRIS, JF
STACEY, FW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (06) : 749 - &
[6] FREE-RADICAL REACTIONS OF FLUOROALKANESULFENYL HALIDES .2. FREE-RADICAL REACTIONS OF TRIFLUOROMETHANESULFENYL CHLORIDE WITH ALKANES
HARRIS, JF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (03) : 931 - &
[7] FREE-RADICAL REACTIONS OF PENTAFLUOROBENZENESULFENYL CHLORIDE WITH ALKANES AND ALKYLBENZENES
HARRIS, JF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (07) : 1319 - 1323
[8] KHARASCH N, 1964, CHEM IND-LONDON, P929
[9] KHARASCH N, 1961, ORGANIC SULFUR COMPO, V1, P375
[10] KLOOSTERZIEL H, 1963, RECL TRAV CHIM PAY B, V82, P508

← 1 2 →