CO2(CO)8-CATALYZED REACTION OF CYCLIC ORTHO ESTERS WITH A HYDROSILANE AND CARBON-MONOXIDE - NOVEL METHOD FOR HOMOLOGATION OF 1,2-DIOLS, 1,3-DIOLS, AND 1,4-DIOLS

被引：19

作者：

CHATANI, N ^{[1
]}

KAJIKAWA, Y ^{[1
]}

NISHIMURA, H ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1021/om00047a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of Co2(CO)8, the reaction of cyclic ortho esters with a hydrosilane and carbon monoxide resulted in the incorporation of carbon monoxide to give diols having one additional carbon atom. The reaction proceeded under mild reaction conditions (0-25-degrees-C, 1 atm of CO).

引用

收藏

页码：21 / 23

页数：3

相关论文

共 9 条

[1] TRIMETHYL- AND TRICHLOROSILYLCOBALT TETRACARBONYLS AND HYDROSILATION OF ETHYLENE [J].

BAAY, YL ;

MACDIARM.AG .

INORGANIC CHEMISTRY, 1969, 8 (04) :986-&

[2] HOMOGENEOUS CATALYSIS .4. SOME REACTIONS OF SILICON HYDRIDES IN PRESENCE OF COBALT CARBONYLS [J].

CHALK, AJ ;

HARROD, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (07) :1640-&

[3] CATALYTIC SILOXYMETHYLATION OF GLYCOSIDES BY THE HSIR3/CO/CO2(CO)8 REACTION - A NEW ENTRY TO C-GLYCOSYL COMPOUNDS [J].

CHATANI, N ;

IKEDA, T ;

SANO, T ;

SONODA, N ;

KUROSAWA, H ;

KAWASAKI, Y ;

MURAI, S .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (14) :3387-3389

[4]

CHATANI N, IN PRESS J ORG CHEMC

[5] VICINAL DIOL CYCLIC SULFATES - LIKE EPOXIDES ONLY MORE REACTIVE [J].

GAO, Y ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (22) :7538-7539

[6] OXYMETHYLATIVE OPENING OF OXIRANES LEADING TO 1,3-DIOL DERIVATIVES BY COBALT CARBONYL CATALYZED REACTION WITH A HYDROSILANE AND CARBON-MONOXIDE [J].

MURAI, T ;

KATO, S ;

MURAI, S ;

TOKI, T ;

SUZUKI, S ;

SONODA, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (20) :6093-6095

[7] COBALT CARBONYL CATALYZED-REACTIONS OF CYCLIC ETHERS WITH A HYDROSILANE AND CARBON-MONOXIDE - A NEW SYNTHETIC REACTION EQUIVALENT TO NUCLEOPHILIC OXYMETHYLATION [J].

MURAI, T ;

YASUI, E ;

KATO, S ;

HATAYAMA, Y ;

SUZUKI, S ;

YAMASAKI, Y ;

SONODA, N ;

KUROSAWA, H ;

KAWASAKI, Y ;

MURAI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (20) :7938-7946

[8] CONVERSION OF DIOLS VIA CYCLIC ORTHOACETATES TO ACETATES OF CHLOROHYDRINS BY TREATMENT WITH TRITYL CHLORIDE [J].

NEWMAN, MS ;

CHEN, CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (01) :278-279

[9] KINETICS AND MECHANISM OF THE SILYLATION OF DICOBALT OCTACARBONYL BY TRIETHYLSILANE - EFFECT OF LEWIS-BASES ON THE REACTION [J].

SISAK, A ;

UNGVARY, F ;

MARKO, L .

ORGANOMETALLICS, 1986, 5 (05) :1019-1023