STRUCTURE OF THE DINUCLEAR PLATINUM MONOHYDRIDO BRIDGED COMPLEX [(PET3)2HPT(MU-H)PTH(PET3)2][BPH4]

被引：12

作者：

BACHECHI, F

机构：

[1] Istituto di Strutturistica Chimica 'G. Giacomello', Roma

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192007674

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Mu-Hydrido)-dihydridotetrakis(triethyl-phosphine)diplatinum(II) tetraphenylborate, [Pt2H3-(C6H15P)4][B(C6H5)4], M(r) = 1185.1, monoclinic, C2/n, a = 23.284 (10), b = 20.923 (7), c = 21.822 (8) angstrom, beta = 93.10 (3)-degrees, V = 10 615 (6) angstrom3, Z = 8, D(x) = 1.483 g cm-3, lambda(Mo Kalpha) 0.71673 angstrom, mu = 54.7 cm-1, F(000) = 4736, T = 293 K, R = 0.074 for 4646 observed reflections. The structure of the cationic complex consists of two Pt-containing units, which lie on reciprocally perpendicular planes. In each unit, the Pt atom is coordinated in a square-planar arrangement, with one terminal hydride ligand and another hydride ligand, bound to both Pt atoms, in a bridging position.

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页码：460 / 464

页数：5

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