X-RAY CRYSTAL-STRUCTURE OF [FERH(CO)(6)(MU-P(T)BU(2))](FE-RH) - A MOLECULE WITH 2 SEMIBRIDGING CARBONYL LIGANDS

被引：5

作者：

HARTUNG, H

KRUG, A

BOTTCHER, HC

机构：

[1] UNIV HALLE WITTENBERG,INST ANORGAN & ALLGEMEINE CHEM,D-06120 HALLE,GERMANY

[2] UNIV HALLE WITTENBERG,INST PHYS CHEM,D-06108 HALLE,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期

关键词：

IRON; RHODIUM; PHOSPHIDO-BRIDGED; CARBONYL; X-RAY STRUCTURE;

D O I：

10.1016/0022-328X(94)05049-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the phosphido-bridged heterobimetallic complex [FeRh(CO)(6)(mu-P(t)Bu(2))] (1) has been established by X-ray analysis. 1 crystallizes in space group P (1) over bar with four molecules per unit cell, the two crystallographically unrelated molecules are practically identical. By ignoring the Fe-Rh bond, the Fe atom has in good approximation a trigonal bipyramidal and the Rh atom an irregular coordination sphere. As indicated by the bonding geometry, two carbonyl ligands of the iron atom are weakly semibridging to the Rh atom.

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页码：C1 / C4

页数：4

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