BIOSYNTHESIS OF ROTENOIDS - ORIGIN OF C-6 AND C-6A

被引：17

作者：

CROMBIE, L

GREEN, CL

WHITING, DA

机构：

[1] Department of Chemistry, University College, Cathays Park

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 24期

关键词：

D O I：

10.1039/j39680003029

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[3-14C]Phenylalanine has been administered to Denis elliptica. The isolated rotenone has 87% of its radioactivity located at C-6a, in accordance with the 1,2-aryl shift previously reported. [Me-14C] Methionine has been fed to Derris elliptica plants, and germinating seeds of Amorpha fructicosa. In both cases the isolated rotenoid was labelled almost entirely at C-6 and the methoxy-groups. In the former case. C-6 of rotenone was supplied to the extent of 0.47-0.51 times the mean figure for a methoxy-group. Similar results (0.50-0.68) were obtained for amorphigenin in the second case.

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页码：3029 / &

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