ARENETRICARBONYLCHROMIUM COMPLEXES IN THE SYNTHESIS OF 6,7-BENZOMORPHANES

被引：4

作者：

KALININ, VN

MOISEEV, SK

BAKHMUTOV, VI

CHEREPANOV, IA

机构：

[1] Nesmeyanov Institute of Organoelement Compounds, Moscow, B-334 117813, Vavilova st.

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 383卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(90)85124-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The action of sodium amide on tricarbonyl-η6-[1′,2′,3′,4′-tetrahydro-spiro(1,3-dioxolane-2,1′-naphthalene)]chromium followed by reaction with sodium bromoacetate gives tricarbonyl-η6-[1-(1,2,3,4-tetrahydro-4-oxonaphthalene)acetic acid]chromium (4). Some procedures to transform 4 into 1-(N-benzyl-2-aminoethyl)-1,2-dihydronaphthalene (10)-a synthon to 6,7-benzomorphanes-are described. Cyclization of 10 by action of mercury(II) acetate yields 3-benzyl-1,2,3,4,5,6-hexahydro-1-hydroxy-2,6-methano-3-benzazocine (11). © 1990.

引用

页码：85 / 91

页数：7

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