PALLADIUM-CATALYZED REACTION OF VINYLIC HALIDES WITH PRIMARY ALLYLIC ALCOHOLS - REGIO AND STEREOCONTROLLED SYNTHESIS OF 4-ENALS

被引:50
作者
JEFFERY, T
机构
[1] Laboratoire de Chimie, l'Ecole Normale Supérieure associé au CNRS, 75231 Paris Cédex 05
关键词
D O I
10.1016/S0040-4039(00)97135-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Stereodefined γ,δ-unsaturated aldehydes can be prepared with high regio and stereocontrol by palladium-catalysed coupling of vinylic halides with primary allylic alcohols, in the presence of silver carbonate and tetra-n-butylammonium hydrogen sulphate. © 1990.
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页码:6641 / 6644
页数:4
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