HOW CARBON-MONOXIDE BONDS TO ALUMINA-SUPPORTED RHODIUM PARTICLES - TUNNELING SPECTROSCOPY MEASUREMENTS WITH ISOTOPES

被引：49

作者：

KROEKER, RM ^{[1
]}

KASKA, WC ^{[1
]}

HANSMA, PK ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

JOURNAL OF CATALYSIS | 1979年 / 57卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0021-9517(79)90044-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Carbon monoxide chemisorbs in at least three different ways on alumina-supported rhodium particles: There are two different linear-bonded species and at least one bridge-bonded species. These conclusions from tunneling measurements on a model catalyst surface are based on isotope shifts with 13CO and C18O. They are in agreement with the conclusions from infrared measurements on dispersed metal catalysts. © 1979.

引用

页码：72 / 79

页数：8

共 23 条

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HANSMA, PK
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