THE 1ST BENZANNULATION CHEMISTRY OF MANGANESE CARBENE COMPLEXES - ACTIVATION BY D(0) METALATION

被引：29

作者：

BALZER, BL ^{[1
]}

CAZANOUE, M ^{[1
]}

SABAT, M ^{[1
]}

FINN, MG ^{[1
]}

机构：

[1] UNIV VIRGINIA, DEPT CHEM, CHARLOTTESVILLE, VA 22901 USA

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 05期

关键词：

D O I：

10.1021/om00041a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fischer arylcarbene complexes of manganese bearing a Ti(IV) substituent, (MeCp)(CO)2MnC(Ar)-(OTiCp2Cl) (Ar = Ph, p-tolyl), undergo benzannulation reactions with 1-hexyne under mild photochemical conditions or in refluxing toluene to afford naphthoquinone products. The analogous manganese alkoxycarbene complexes are unreactive. Preliminary tests of the reaction mechanism are not consistent with the expected photolytic dissociation of CO ligand from manganese.

引用

页码：1759 / 1761

页数：3

共 23 条

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