SYNTHESIS AND STRUCTURE OF [ET2BI(OAR)]INFINITY(AR = C6F5, PH) - A NEW INORGANIC CHAIN POLYMER

被引：26

作者：

WHITMIRE, KH

HUTCHISON, JC

MCKNIGHT, AL

JONES, CM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 14期

关键词：

D O I：

10.1039/c39920001021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triethylbismuth reacts slowly with HOAr (Ar = C6F5, Ph) in refluxing toluene to yield the compounds [BiEt2OAr]infinity which are shown by single crystal X-ray diffraction to exist as chiral chain polymers in which bridging alkoxides join Et2Bi groups containing a stereoactive lone pair of electrons.

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页码：1021 / 1022

页数：2

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