PREPARATION AND ELECTRICAL-PROPERTIES OF FERROELECTRIC (PB,LA)(ZR,TI)O-3 THIN-FILMS BY METALORGANIC CHEMICAL-VAPOR-DEPOSITION

被引:9
作者
TOMINAGA, K [1 ]
SAKASHITA, Y [1 ]
NAKASHIMA, H [1 ]
OKADA, M [1 ]
机构
[1] CHUBU UNIV,FAC ENGN,DEPT IND CHEM,KASUGAI,AICHI 487,JAPAN
关键词
D O I
10.1016/0022-0248(94)91054-5
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Lanthanum-modified lead zirconate titanate (PLZT) thin films have been epitaxially grown on MgO (100) and Pt/SiO2/Si substrates at 650 degrees C by the metalorganic chemical vapor deposition (MOCVD) method. The properties of the films were examined as a function of lanthanum content. The films were of a single perovskite structure, and highly oriented to the c-axis of the tetragonal phase on a MgO (100) substrate. The films were transformed from tetragonal to nearly cubic as the La content increased. The relative dielectric constants increased, and the remanent polarization and coercive field decreased as the La content increased. The switching time and leakage current densities decreased with increasing La content. The fatigue of the films was relaxed as the La content increased. The fatigue of the PLZT films does not occur below 1.0 x 10(13) cycles at a working voltage of 3 V by means of the acceleration test.
引用
收藏
页码:219 / 225
页数:7
相关论文
共 13 条
[1]  
HAERTLING GH, 1971, J AM CERAM SOC, V54, P1, DOI [10.1111/j.1151-2916.1970.tb12105.x-i1, 10.1111/j.1151-2916.1971.tb12296.x]
[2]  
Hamada H., 1979, Oyo Buturi, V48, P602
[3]   PREPARATION AND SWITCHING KINETICS OF PB(ZR, TI)O3 THIN-FILMS DEPOSITED BY REACTIVE SPUTTERING [J].
HASE, T ;
SHIOSAKI, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1991, 30 (9B) :2159-2162
[4]   THERMODYNAMIC THEORY OF THE LEAD ZIRCONATE-TITANATE SOLID-SOLUTION SYSTEM, .5. THEORETICAL CALCULATIONS [J].
HAUN, MJ ;
FURMAN, E ;
JANG, SJ ;
CROSS, LE .
FERROELECTRICS, 1989, 99 :63-86
[5]  
IIJIMA K, 1986, J APPL PHYS, V60, P1
[6]   PROPERTIES OF PIEZOELECTRIC CERAMICS IN THE SOLID-SOLUTION SERIES LEAD TITANATE-LEAD ZIRCONATE-LEAD OXIDE - TIN OXIDE AND LEAD TITANATE-LEAD HAFNATE [J].
JAFFE, B ;
ROTH, RS ;
MARZULLO, S .
JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1955, 55 (05) :239-254
[7]   PREPARATION AND PROPERTIES OF (PB,LA)(ZR,TI)O3 THIN-FILMS BY METALORGANIC CHEMICAL VAPOR-DEPOSITION [J].
OKADA, M ;
TOMINAGA, K .
JOURNAL OF APPLIED PHYSICS, 1992, 71 (04) :1955-1959
[8]   PREPARATION OF C-AXIS-ORIENTED PBTIO3 THIN-FILMS BY MOCVD UNDER REDUCED PRESSURE [J].
OKADA, M ;
TAKAI, S ;
AMEMIYA, M ;
TOMINAGA, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1989, 28 (06) :1030-1034
[9]  
OKADA M, 1988, J CERAM SOC JPN, V96, P676
[10]  
OKADA M, 1989, JPN J APPL PHYS, V29, P718