SYNTHETIC APPROACH TO 4-DEOXY-4,4-DIFLUOROPYRANOSIDES VIA CYCLOADDITION OF 2,4-DIALKOXY-1,1-DIFLUORO-1,3-DIENES WITH ALDEHYDES

被引：15

作者：

TAGUCHI, T

KODAMA, Y

KANAZAWA, M

机构：

[1] Tokyo College of Pharmacy, Hachioji, Tokyo, 192-03

来源：

CARBOHYDRATE RESEARCH | 1993年 / 249卷 / 01期

关键词：

D O I：

10.1016/0008-6215(93)84072-E

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Preparation of the 2,4-dialkoxy-l,1-difluoro-1,3-diene and its Lewis acid-catalyzed cycloaddition with aldehydes leading to 3,3-difluoro-2,3-dihydro-6H-pyrans (3) are described. Compound 3 and the derived 4-deoxy-4,4-difluoroglycal were found potentially useful as glycosyl donors.

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页码：243 / 252

页数：10

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