REGIOSELECTIVITY IN THE REDUCTIVE ACYLOXYLATION OF ALPHA,ALPHA'-DIBROMO KETONES

被引：8

作者：

FRY, AJ

LEFOR, AT

机构：

[1] Hall-Atwater Laboratories of Chemistry, Wesleyan University, Connecticut, Middletown

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 08期

关键词：

D O I：

10.1021/jo01322a018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reduction, either electrochemically or by ultrasonically-dispersed mercury, of a series of 2, 4-dibromo-2-methyl-4-alkyl-3-butanones (alkyl = H, Me, Et, i-Pr, t-Bu, neopentyl) was carried out in a variety of solvent systems. It was possible to identify conditions under which either of the two possible isomeric -acyloxy ketones could be made to predominate, and a number of examples of highly regioselective reactions were observed. © 1979, American Chemical Society. All rights reserved.

引用

页码：1270 / 1273

页数：4

共 15 条

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