LINKAGE POSITION DETERMINATION IN OLIGOSACCHARIDES - MS/MS STUDY OF LITHIUM-CATIONIZED CARBOHYDRATES

被引:182
作者
ZHOU, ZR [1 ]
OGDEN, S [1 ]
LEARY, JA [1 ]
机构
[1] UNIV CALIF BERKELEY,COLL CHEM,BERKELEY,CA 94720
关键词
D O I
10.1021/jo00307a011
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Tandem mass spectrometry of the [M + 2Li - H]+ ion of isomeric disaccharides is used to distinguish differences in the linkage position of the glycosidic bond. This technique can be applied to larger oligosaccharides with mixed linkages and still allow for correct determination of position and type of linkage. © 1990, American Chemical Society. All rights reserved.
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页码:5444 / 5446
页数:3
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