KINETIC RESOLUTION OF 1-METHYL-1-PHENYLPROPYL HYDROPEROXIDE VIA SHARPLESS EPOXIDATION

被引:8
作者
HOFT, E
HAMANN, HJ
KUNATH, A
RUFFER, L
机构
[1] Centre of Organic Synthesis, O- 1199 Berlin-Adlershof
关键词
D O I
10.1016/S0957-4166(00)80252-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The kinetic resolution of 1-methyl-1-phenylpropyl hydroperoxide via catalytic Sharpless epoxidation with various allylic alcohols has been investigated. An enantiomeric excess of nearly 20 % of the resolved hydroperoxide has been observed.
引用
收藏
页码:507 / 510
页数:4
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