SYNTHESIS OF 2-(SUBSTITUTED METHYL)-3,4-DISUBSTITUTED PYRROLES AND THEIR CONVERSION INTO THE CORRESPONDING PORPHYRINS

被引：10

作者：

KINOSHITA, H ^{[1
]}

TANAKA, S ^{[1
]}

NISHIMORI, N ^{[1
]}

DEJIMA, H ^{[1
]}

INOMATA, K ^{[1
]}

机构：

[1] KANAZAWA UNIV, FAC SCI, DEPT CHEM, MARUNOUCHI 1-1, KANAZAWA, ISHIKAWA 920, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 10期

关键词：

D O I：

10.1246/bcsj.65.2660

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Hydroxymethyl-1-methylsulfonyl-3,4-disubstituted pyrroles and 2-hydroxymethyl-3,4-disubstituted pyrroles were effectively converted into the corresponding 2-(substituted methyl)pyrrole derivatives by the reaction with various nucleophiles in the presence of base. These products were further transformed to the corresponding porphyrins regioselectively under almost neutral or basic conditions.

引用

页码：2660 / 2667

页数：8

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