CHIRALLY ARRANGED MONOMERIC DYES ON HELICAL BILAYER-MEMBRANES

被引：12

作者：

HACHISAKO, H ^{[1
]}

IHARA, H ^{[1
]}

HIRAYAMA, C ^{[1
]}

YAMADA, K ^{[1
]}

机构：

[1] KUMAMOTO UNIV,FAC ENGN,DEPT APPL CHEM,KUMAMOTO 860,JAPAN

来源：

LIQUID CRYSTALS | 1993年 / 13卷 / 02期

关键词：

D O I：

10.1080/02678299308026304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Strong exciton coupling around the absorption band of monomeric dyes was induced by helical bilayer membranes formed from various L-glutamic acid-derived amphiphiles which contain three amides per molecule. The mirror-image of the circular dichroism spectra was observed by the corresponding D-isomers. No similar induction was observed by the corresponding ester-type amphiphiles which could not produce helices. It is assumed that dyes are helically arranged on helical bilayer membranes, resulting in an induction of chirality even in monomeric dyes.

引用

页码：307 / 311

页数：5

共 20 条

[1]

BALLARD RE, 1986, BIOPOLYMERS, V4, P97

[2] ONE-DIMENSIONAL AROMATIC CRYSTALS IN SOLUTION .4. GROUND-STATE AND EXCITED-STATE INTERACTIONS OF POLY(L-1-PYRENYLALANINE) STUDIED BY CHIROPTICAL SPECTROSCOPY INCLUDING CIRCULARLY POLARIZED FLUORESCENCE AND FLUORESCENCE-DETECTED CIRCULAR-DICHROISM [J].

EGUSA, S ;

SISIDO, M ;

IMANISHI, Y .

MACROMOLECULES, 1985, 18 (05) :882-889

[3]

EGUSA S, 1985, MACROMOLECULES, V18, P890

[4] EXTRAORDINARY MONOMER-DIMER TRANSITION OF METHYLENE-BLUE INDUCED BY THE PHASE-TRANSITION OF TELOMERBILAYER MEMBRANES FORMED FROM DIALKYL L-GLUTAMATE AMPHIPHILES WITH OLIGO-ACRYLIC ACID-HEAD GROUP [J].

HACHISAKO, H ;

MOTOZATO, Y ;

MURAKAMI, R ;

YAMADA, K .

CHEMISTRY LETTERS, 1992, (02) :219-222

[5] INDUCED OPTICAL-ACTIVITY IN POLY-L-LYSINE METHYL ORANGE SYSTEM [J].

HATANO, M ;

YONEYAMA, M ;

SATO, Y ;

KAWAMURA, Y .

BIOPOLYMERS, 1973, 12 (10) :2423-2430

[6] RELATIONSHIP BETWEEN FORMATION OF HELICAL BILAYER-MEMBRANES AND CHEMICAL STRUCTURES OF DIALKYL AMPHIPHILES WITH POLYPEPTIDE-HEAD GROUP [J].

IHARA, H ;

YOSHIKAI, K ;

TAKAFUJI, M ;

HIRAYAMA, C ;

YAMADA, K .

KOBUNSHI RONBUNSHU, 1991, 48 (05) :327-334

[7] PRODUCTION OF HELICAL BILAYER-MEMBRANES FROM L-GLUTAMIC ACID-DERIVATIVES WITH BIS(DODECYLAMIDE) GROUPS AND THEIR SPECIFIC OPTICAL-ACTIVITY [J].

IHARA, H ;

YAMAGUCHI, M ;

TAKAFUJI, M ;

HACHISAKO, H ;

HIRAYAMA, C ;

YAMADA, K .

NIPPON KAGAKU KAISHI, 1990, (10) :1047-1053

[8] AMPHIPHILES WITH POLYPEPTIDE-HEAD GROUPS .5. SPECIFIC BINDINGS OF METHYL-ORANGE TO CHIRAL BILAYER-MEMBRANES WITH BETA-ALANYL-L-GLUTAMOYL HEAD GROUPS [J].

IHARA, H ;

HACHISAKO, H ;

HIRAYAMA, C ;

YAMADA, K .

LIQUID CRYSTALS, 1987, 2 (02) :215-221

[9]

MURAKAMI Y, 1990, SUPRAMOLECULAR ASSEM, P17

[10] LARGE INDUCED CIRCULAR-DICHROISM OF METHYL-ORANGE BOUND TO CHIRAL BILAYER-MEMBRANES - ITS EXTREME SENSITIVITY TO THE PHASE-TRANSITION AND THE CHEMICAL-STRUCTURE OF THE MEMBRANE [J].

NAKASHIMA, N ;

FUKUSHIMA, H ;

KUNITAKE, T .

CHEMISTRY LETTERS, 1981, (09) :1207-1210

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