ELECTROCHEMICAL SYNTHESIS OF EXTENDED TTF

被引:92
作者
LORCY, D
CARLIER, R
ROBERT, A
TALLEC, A
LEMAGUERES, P
OUAHAB, L
机构
[1] UNIV RENNES,ELECTROCHIM ORGAN LAB,CNRS,UA 439,F-35042 RENNES,FRANCE
[2] UNIV RENNES,CHIM SOLIDE & INORGAN MOLEC LAB,CNRS,UA 1495,F-35042 RENNES,FRANCE
关键词
D O I
10.1021/jo00113a026
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient electrochemical synthesis of new extended TTFs (tetrathiafulvalenes) starting from 1,4-dithiafulvenes is presented, and the mechanism is discussed. Single crystal X-ray structure of the neutral extended TTF 7d is reported. These novel pi-electron donor molecules show one two-electron reversible oxidation wave in cyclic voltammetry.
引用
收藏
页码:2443 / 2447
页数:5
相关论文
共 26 条
  • [1] SYNTHESIS OF 1,4-DITHIAFULVENES AND 1,4-DITHIAFULVALENES BY CARBONYL OLEFINATION USING 2-DIMETHOXYPHOSPHINYL-1,3-BENZODITHIOLE
    AKIBA, KY
    ISHIKAWA, K
    INAMOTO, N
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (09) : 2674 - 2683
  • [2] 2,5-BIS(1,4-DITHIAFULVEN-6-YL) FURANS, THIOPHENES AND N-METHYL PYRROLES AS EXTENDED ANALOGS OF TETRATHIAFULVALENE
    BENAHMEDGASMI, AS
    FRERE, P
    GARRIGUES, B
    GORGUES, A
    JUBAULT, M
    CARLIER, R
    TEXIER, F
    [J]. TETRAHEDRON LETTERS, 1992, 33 (43) : 6457 - 6460
  • [3] NEW VINYLOGOUS TETRATHIAFULVALENE PI-ELECTRON DONORS WITH PERIPHERAL ALKYLSELENO SUBSTITUTION
    BRYCE, MR
    COFFIN, MA
    CLEGG, W
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (06) : 1696 - 1699
  • [4] CAVA MP, 1980, J HETEROCYCLIC CHEM, V17, pS39
  • [5] NEW EXTENDED PI-ELECTRON DONORS - TETRATHIAFULVALENE SYSTEMS WITH HETEROCYCLIC SPACER GROUPS
    HANSEN, TK
    LAKSHMIKANTHAM, MV
    CAVA, MP
    NIZIURSKIMANN, RE
    JENSEN, F
    BECHER, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) : 5035 - 5039
  • [6] APPLICATIONS OF THE 1,3-DITHIOLE UNIT IN A POST-TTF ERA
    HANSEN, TK
    BECHER, J
    [J]. ADVANCED MATERIALS, 1993, 5 (04) : 288 - 292
  • [7] SYNTHESIS AND PROPERTIES OF NEW PI-DONOR SULFUR HETEROCYCLES
    HANSEN, TK
    LAKSHMIKANTHAM, MV
    CAVA, MP
    METZGER, RM
    BECHER, J
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (08) : 2720 - 2722
  • [8] KIRMSE W, 1958, LIEBIGS ANN CHEM, V614, P4
  • [9] KRIEF A, 1986, TETRAHEDRON, V42, P1209
  • [10] LORCY D, 1994, B SOC CHIM FR, V131, P774