SYNTHESIS OF A POLYMER-SUPPORTED O-PHENYLENE(DIPHOSPHINE) AND CHARACTERIZATION OF SOME METAL-COMPLEXES

被引：8

作者：

CHAMPNESS, NR

LEVASON, W

OLDROYD, RD

GULLIVER, DJ

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,ENGLAND

[2] BP CHEM,HULL RES & TECHNOL CTR,KINGSTON HULL HU12 8DS,N HUMBERSIDE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期

关键词：

NICKEL; PLATINUM; RHODIUM; RUTHENIUM; DIPHOSPHINE; POLYMER; SUPPORTED CATALYST;

D O I：

10.1016/0022-328X(94)87066-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis is described of the polymer-supported diphosphine, PolPP, in which an o-C6H3(PPh(2))(2) unit is linked via a -CH2O group in the 4-position of the benzene ring to a Merrifield resin. The preparations of the complexes (PolPP)NiCl2, (PolPP)PtCl2, (PolPP>Rh(PPh(3))Cl and (PolPP)Ru(PPh(3))Cl-2 and related model compounds are reported, and their characterization by UV-visibIe spectroscopy and metal edge EXAFS is described.

引用

页码：275 / 281

页数：7

共 37 条

[1] AKITT JW, 1973, NMR CHEM, P45
[2] CRYSTAL AND MOLECULAR-STRUCTURE OF ORANGE AND RED ALLOTROPES OF CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
BENNETT, MJ
DONALDSON, PB
[J]. INORGANIC CHEMISTRY, 1977, 16 (03) : 655 - 660
[3] BINSTED N, 1988, PAXAS
[4] BINSTED N, 1992, SERC DARESBURY LABOR
[5] COORDINATION CHEMISTRY OF HIGHER OXIDATION-STATES .40. SPECTROSCOPIC, ELECTROCHEMICAL AND STRUCTURAL STUDIES OF CATIONIC OSMIUM-(III) AND OSMIUM-(IV) DIPHOSPHINE AND DIARSINE COMPLEXES
CHAMPNESS, NR
LEVASON, W
PLETCHER, D
SPICER, MD
WEBSTER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (14): : 2201 - 2207
[6] CHAMPNESS NR, 1990, UNPUB
[7] COORDINATION CHEMISTRY OF HIGHER OXIDATION-STATES .35. SYNTHETIC, SPECTROSCOPIC, AND ELECTROCHEMICAL STUDIES OF SOME MER-[OSL3X3] [OSL3X3]+ AND FAC-[OSL3X3]/[OSL3X3]+ SYSTEMS (L = PR3, ASR3, SBR3, OR PYRIDINE-X = CL OR BR) - CRYSTAL-STRUCTURE OF FAC-[OS(PET2PH)3CL3].CH2CL2
CIPRIANO, RA
LEVASON, W
MOULD, RAS
PLETCHER, D
WEBSTER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08): : 2609 - 2616
[8] ASYMMETRIC CATALYTIC REDUCTION WITH TRANSITION-METAL COMPLEXES .2. ASYMMETRIC CATALYSIS BY A SUPPORTED CHIRAL RHODIUM COMPLEX
DUMONT, W
POULIN, J
DANG, T
KAGAN, HB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (25) : 8295 - 8299
[9] CRYSTAL-STRUCTURES OF BIS[(ETHANE-1,2-DIYL)BIS(DIPHENYLPHOSPHINE)]-PALLADIUM(II) AND PLATINUM(II) DICHLORIDE DICHLOROMETHANE AND DICHLORO[(ETHANE-1,2-DIYL)BIS(DIPHENYLPHOSPHINE)]PLATINUM(II) DICHLOROMETHANE
ENGELHARDT, LM
PATRICK, JM
RASTON, CL
TWISS, P
WHITE, AH
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (11) : 2193 - 2200
[10] FRECHET JM, 1971, J AM CHEM SOC, V93, P492

← 1 2 3 4 →