REACTIONS OF RADICALS CONTAINING FLUORINE .V. ADDITION OF TRIFLUOROMETHYL RADICALS TO ETHYLENE

被引：24

作者：

SANGSTER, JM

THYNNE, JCJ

机构：

[1] Chemistry Department, Edinburgh University, Edinburgh

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 08期

关键词：

D O I：

10.1021/j100842a049

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The addition of trifluoromethyl radicals to ethylene in the gas phase has been studied over the temperature range 18-201° using the abstraction of a hydrogen atom from hydrogen sulfide as the competing reaction. The Arrhenius parameters determined for the addition reaction were 1011.39 mol-1 cm-3 sec-1 and 2.4 kcal mol-1.

引用

页码：2746 / &

共 11 条

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