AMINO-ACIDS ATTACHED TO POLY(ALKYLENE PHOSPHATE)S .1. SYNTHESIS

被引：10

作者：

KALUZYNSKI, K ^{[1
]}

PENCZEK, S ^{[1
]}

机构：

[1] POLISH ACAD SCI, CTR MOLEC & MACROMOLEC STUDIES, SIENKIEWICZA 112, PL-90363 LODZ, POLAND

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1994年 / 195卷 / 12期

关键词：

D O I：

10.1002/macp.1994.021951211

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of poly(alkylene phosphate)s with attached amino acids was elaborated. Two methods of coupling through P-NH bond were used. They were based on the direct reaction of amino acid esters or N,O-bis(trimethylsilyl) substituted amino acids with poly(alkylene chlorophosphate)s. The assumed microstructure of the resulting polymers was confirmed by analysis of the H-1, C-13 and P-31 NMR spectra. Preliminary data on the hydrolytic stability of amino acids modified poly(alkylene phosphate)s are also given.

引用

页码：3855 / 3862

页数：8

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