TEMPERATURE-DEPENDENCE OF CATION DISTRIBUTION IN FERRIMAGNETIC SPINELS

被引：4

作者：

BORGHESE, C

机构：

[1] Research Group, Ceramic Laboratory of Selenia S.p.A., Rome

来源：

JOURNAL OF MATERIALS SCIENCE | 1969年 / 4卷 / 01期

关键词：

D O I：

10.1007/BF00555047

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The cation distribution at some equilibrium temperature in ferrimagnetic spinels can be inferred provided the contributions to the cationic site energies are established. In some compounds, e.g. magnesioferrite, the distribution is strongly dependent on temperature. This is explained by taking into account suitable thermal energy terms in addition to electrostatic or crystal-field octahedral stabilisations. The Fe3O4/MgδFe3-δO4-(δ-1)/2 system is considered and the temperature-dependence in magnesioferrite is discussed. A comparison is made of the theoretical derivation with several experimental data. © 1969 Chapman and Hall.

引用

页码：50 / &

共 29 条

[1]

ANDERSON OL, 1965, PHYSICAL ACOUSTICS B, P62

[2] FERROMAGNETIC RESONANCE ABSORPTION MAGNETITE [J].