CRYSTAL-FIELD-INDUCED CONFIGURATION INTERACTION IN CONFIGURATION (L1 + L2)

被引：5

作者：

ARMSTRONG, L

机构：

[1] Physics Department, Johns Hopkins University, Baltimore

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 01期

关键词：

D O I：

10.1063/1.1671696

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Effective operators are obtained which reproduce, to second order in perturbation theory, the effects of crystal-field-induced configuration interaction on the energy levels of the configuration (l1+l 2)n. Techniques of second quantization are used to carry out the calculation. Many effects of the configuration interaction are found to be absorbed by the first-order crystal-field terms. The results are discussed in relation to similar calculations made of the structure of the configuration ln by Rajnak and Wybourne.

引用

页码：129 / +

页数：1

共 10 条

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