PROTON MAGNETIC RESONANCE STUDIES OF COMPOUNDS WITH BRIDGHEAD NITROGEN ATOMS .10. CONFIGURATIONAL AND CONFORMATIONAL STUDIES WITH METHYL SUBSTITUTED PERHYDROPYRIDO [1,2-C]PYRROLO[2,1-E] IMIDAZOLES

被引:14
作者
CHIVERS, PJ
CRABB, TA
WILLIAMS, RO
机构
[1] Chemistry Department, Portsmouth College of Technology, London
关键词
D O I
10.1016/0040-4020(69)80034-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of Me substituted perhydropyrido [1,2-c]pyrrolo [2,1-e] imidazoles have been synthesized and their configurations and preferred conformations assigned on the basis of the 2800-2700 cm-1 region of their IR spectra and from a study of their PMR spectra with particular reference to the geminal coupling constant of the C6 methylene protons. The influence of dipole interactions in determining conformational preferences in these compounds is discussed. © 1969.
引用
收藏
页码:2921 / &
相关论文
共 16 条