A NEW CONVENIENT METHOD FOR THE SYNTHESIS OF CHIRAL C3-SYNTHONS

被引：29

作者：

EMONS, CHH ^{[1
]}

KUSTER, BFM ^{[1
]}

VEKEMANS, JAJM ^{[1
]}

SHELDON, RA ^{[1
]}

机构：

[1] EINDHOVEN UNIV TECHNOL,CHEM TECHNOL LAB,POB 513,5600 MB EINDHOVEN,NETHERLANDS

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)82119-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Routes are described for the facile preparation of protected optically pure D- and L-glyceric acid (1a,b; 2a,b) starting from D-mannitol, D-isoascorbic acid and L-ascorbic acid. The key step is a ruthenium catalyzed oxidative cleavage of the vicinal diols 4a,b or the alpha-hydroxy acids 7a,b; 10a,b.

引用

页码：359 / 362

页数：4

共 31 条

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