DETAILED EQUILIBRIUM PRINCIPLE IN REVERSIBLE BIMOLECULAR DIFFUSION-CONTROLLED REACTIONS

被引：19

作者：

BURLATSKY, SF ^{[1
]}

LEVIN, PP ^{[1
]}

KHUDYAKOV, IV ^{[1
]}

KUZMIN, VA ^{[1
]}

OVCHINNIKOV, AA ^{[1
]}

机构：

[1] LY KARPOV PHYSICOCHEM RES INST,MOSCOW,USSR

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80340-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The expressions for the observed rate constants of the forward bimolecular and back monomolecular reactions have been obtained using the boundary conditions imposed upon the reaction surfaces of each reagent particle. The rate, equilibrium and thermodynamical parameters of the back dissociation reactions of phenoxy radical dimers have been measured. The resultant values of kobs-1 as a function of solvent viscosity are accurately described by theoretical relationships obtained in the present work. © 1979.

引用

页码：565 / 569

页数：5

共 9 条

[1] ON DIFFUSION-CONTROLLED DISSOCIATION
BERG, OG
[J]. CHEMICAL PHYSICS, 1978, 31 (01) : 47 - 57
[2] CALDIN EF, 1975, J CHEM SOC F1, P515
[3] DIFFUSION-CONTROLLED REACTION RATES
COLLINS, FC
KIMBALL, GE
[J]. JOURNAL OF COLLOID SCIENCE, 1949, 4 (04): : 425 - 437
[4] KHUDYAKOV IV, UNPUBLISHED
[5] KHUDYAKOV IV, 1978, IAN SSSR KH, P1492
[6] KHUDYAKOV IV, 1977, 3RD P C DEGR STAB PO
[7] NOYES RM, 1961, PROG REACT KINET MEC, V1, P129
[8] OVCHINNIKOV AA, 1978, DOKL AKAD NAUK SSSR+, V239, P643
[9] SHURR JM, 1970, BIOPHYS J, V10, P700

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