CRYSTAL-STRUCTURE OF A 7-COORDINATE COBALT(II) COMPLEX WITH A NEW POLYFUNCTIONAL HYDRAZONIC LIGAND, [CO(H4DAPIS)(OH2)2]CL2.9/2H2O

被引：8

作者：

BELLETTI, D ^{[1
]}

CARCELLI, M ^{[1
]}

PELIZZI, C ^{[1
]}

PELIZZI, G ^{[1
]}

机构：

[1] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,IST CHIM GEN & INORGAN,I-43100 PARMA,ITALY

来源：

JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1992年 / 22卷 / 02期

关键词：

D O I：

10.1007/BF01186255

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A seven-coordinate cobalt(II) complex has been synthesized with a new hydrazonic ligand, H-4dapis, and its crystal structure determined by X-ray diffraction methods and refined to R 0.0564 for 2763 independent reflections. The structure consists of [Co(H-4dapis)(OH2)2] Cations, Cl anions, and lattice H2O molecules interlinked by hydrogen bonds. The cobalt atom has a distorted pentagonal bipyramidal environment with two axial H2O molecules and the H-4dapis ligand forming the basal plane.

引用

页码：185 / 191

页数：7

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