VIBRATIONAL SPECTROSCOPY AT THE ELECTROCHEMICAL INTERFACE

被引：56

作者：

IWASITA, T

NART, FC

RODES, A

PASTOR, E

WEBER, M

机构：

[1] Institut für Physikalische Chemie der Universität Bonn, 53115 Bonn

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 01期

关键词：

SULFATE ADSORPTION; CARBONATE ADSORPTION; FTIR; PT SINGLE CRYSTAL;

D O I：

10.1016/0013-4686(94)00239-W

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Results of in situ infrared investigations of the electrochemical interface using well defined metal surfaces are discussed. Spectral analysis on the adsorption of ions allow to establish the nature of the adsorbed species, the adsorption geometry and the interactions operating at the interface. This is demostrated for carbonate and sulfate ions adsorbed on the basal planes of Pt single crystal electrodes.

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页码：53 / 59

页数：7

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