TRANSITION-METAL CARBYNE COMPLEXES .48. COMPLEX-STABILIZED HYDROXY(PARA-TOLYL)ACETYLENE BY REACTION OF TRANS-CHLOROTETRACARBONYL(TOLYLCARBYNE)TUNGSTEN WITH ACETYLACETONE

被引：36

作者：

FISCHER, EO

FRIEDRICH, P

机构：

[1] Anorganisch-Chemisches Institut, Technischen Universität München, Garching, D-8046

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 04期

关键词：

D O I：

10.1002/anie.197903271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An “acetylene alcohol”, which is stabilized by coordination to a transition metal to atom, arises on photochemical reduction of the carbyne complex 1 with acetylacetone. Crystal structure analysis shows the acetylene C atoms to be symmetrically bonded to the W atom. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：327 / 328

页数：2

共 19 条

[1] [Anonymous], 1977, ANGEW CHEM, V89, P481
[2] BOND CHARACTER OF BETA-DIKETONE METAL CHELATES
BOCK, B
FLATAU, K
JUNGE, H
KUHR, M
MUSSO, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1971, 10 (04) : 225 - &
[3] Bock B., 1971, ANGEW CHEM, V83, P239
[4] CRYSTAL AND MOLECULAR-STRUCTURE OF OXO-PI-CYCLOPENTADIENYL-PI-DIPHENYLACETYLENE-SIGMA-PHENYLTUNGSTEN
BOKIY, NG
GATILOV, YV
STRUCHKO.YT
USTYNYUK, NA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 54 (JUN16) : 213 - 219
[5] DAO NQ, CHEM BER
[6] TRANSITION-METAL CARBYNE COMPLEXES .18. REACTIONS INVOLVING REPLACEMENT OF CARBONYL GROUPS IN TRANS-BROMOTETRACARBONYL(PHENYLCARBYNE)COMPLEXES OF CHROMIUM AND TUNGSTEN
FISCHER, EO
RUHS, A
KREISSL, FR
[J]. CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (03): : 805 - 815
[7] TRANSITION METAL-CARBYNE COMPLEXES .32. SYNTHESIS OF ALKYNE-BRIDGED DINUCLEAR COMPLEXES BY REACTION OF TRANS-HALOTETRACARBONYL(METHYLCARBYNE)-TUNGSTEN WITH METHYLENEBIS(DIPHENYLARSANE)
FISCHER, EO
RUHS, A
FRIEDRICH, P
HUTTNER, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (07): : 465 - 466
[8] TRANSITION-METAL CARBYNE COMPLEXES .7. PREPARATION, PROPERTIES AND REACTIVITY OF TRANSITION-METAL CARBONYL CARBYNE COMPLEXES
FISCHER, EO
SCHUBERT, U
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 100 (01) : 59 - 81
[9] INVESTIGATION OF BIOLOGICALLY-ACTIVE LIGANDS .10. H-1 AND C-13 NMR-SPECTRA OF MALEIC ACID HYDRAZIDE AND ITS N-METHYL DERIVATIVE
FRITZ, HP
KOHLER, FH
LIPPERT, B
[J]. CHEMISCHE BERICHTE-RECUEIL, 1973, 106 (09): : 2918 - 2924
[10] GILLIERPANDRAUD H, 1967, B SOC CHIM FR, P1988

← 1 2 →