Reactions of silyl- and germyllithium compounds with azoxybenzene

被引：13

作者：

George, M. V. ^{[1
]}

Talukdar, Purnendu B. ^{[1
]}

Gerow, Clare W. ^{[1
]}

Gilman, Henry ^{[1
]}

机构：

[1] Iowa State Univ, Chem Lab, Ames, IA 50011 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1960年 / 82卷 / 17期

关键词：

D O I：

10.1021/ja01502a029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of triphenylsilyllithium with azoxybenzene gives N,N'-diphenyl-N-triphenylsilylliydrazine, a compound previously prepared by the direct addition of triphenylsilyllithium to azobenzene. Similarly, diphenylmethylsilyllithium and triphenylgermyllithium give N,N'-diphenyl-N-diphenylmethylsilylhydrazine and N,N'-diphenyl-N-triphenylgermylhvdrazine, respectively. In these reactions it has been observed that azoxybenzene is first reduced to azobenzene which then reacts with the silyl- or germyllithium compound to give the corresponding addition products.

引用

页码：4562 / 4564

页数：3

共 17 条

[1]

BACHMANN WE, 1931, J AM CHEM SOC, V53, P1524

[2]

BRADY LJ, 1948, IND ENG CHEM ANAL ED, V20, P1034

[3] THE PREPARATION OF SOME TRIARYLAMINOSILANES [J].