THIOLATE ANION AS A NUCLEOPHILE .8. REACTIONS OF DIBROMOTETRAFLUOROBENZENES

被引：8

作者：

FRAZEE, WJ

PEACH, ME

机构：

[1] Chemistry Department, Acadia University, Wolfville

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1979年 / 13卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)82090-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the isomeric dibrometetrafluorobenzenes with the methanethiolate anion and copper(I) methanethiolate have been examined. Using the thiolate anion replacement of fluorine by the SMe group occurred, but with copper(I) methanethiolate protodebromination and replacement of the bromine with the SMe group occurred. The new compounds isolated have been characterized and their spectra (NMR, IR, and mass) examined. © 1979.

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页码：225 / 233

页数：9

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