H-1 AND C-13 NMR ANALYSIS OF BRASSINOSTEROIDS

被引：23

作者：

PORZEL, A

MARQUARDT, V

ADAM, G

MASSIOT, G

ZEIGAN, D

机构：

[1] INST PLANT BIOCHEM,WEINBERG 3,PF 250,O-4010 HALLE,GERMANY

[2] FAC PHARM REIMS,CNRS,UA 492,F-51096 REIMS,FRANCE

[3] ANALYT CTR,O-1199 BERLIN,GERMANY

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1992年 / 30卷 / 07期

关键词：

BRASSINOSTEROIDS; H-1 AND C-13 CHEMICAL SHIFT ASSIGNMENT; PARTIALLY RELAXED H-1 COSY; RELAYED COSY; XHCORRD; HMQC; HMBC;

D O I：

10.1002/mrc.1260300714

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The H-1 and C-13 NMR spectra of the two phytohormones, brassinolide and 24-epi-brassinolide, and the two synthetic analogues 22,23,24-trisepi-brassinolide and (22S,23S)-28-homo-brassinolide, were assigned using ID and 2D NMR techniques. Independent assignment strategies are presented for the H-1 and C-13 chemical shifts of the steroidal side-chain.

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收藏

页码：651 / 657

页数：7

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