ELECTROCHEMISTRY OF OSMIUM IN SODIUM HYDROXIDE SOLUTIONS +8, +6, AND +4 STATES

被引：19

作者：

CONNERY, JG

COVER, RE

机构：

[1] Department of Chemistry, St. John’s University, N.Y. 11432, Jamaica

来源：

ANALYTICAL CHEMISTRY | 1968年 / 40卷 / 01期

关键词：

D O I：

10.1021/ac60257a025

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Constant-current coulometry and voltammetry were used to elucidate the nature of the various species present in sodium hydroxide solutions of osmium(IV) and osmium(VI). The existence of three osmium(VI) species, three osmium(IV) species, and an electroactive solid has been demonstrated and their chemical natures deduced. The conclusions are consistent with all data available on osmium behavior in these media. © 1968, American Chemical Society. All rights reserved.

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页码：87 / &

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