HOLE DELOCALIZATION IN NAPHTHALOCYANINATOPHTHALOCYANINATOLUTETIUM(III)

被引：68

作者：

ISHIKAWA, N

OHNO, O

KAIZU, Y

机构：

[1] Department of Chemistry, Tokyo Institute of Technology, 152, O-okayama, Meguroku Tokyo

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 180卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(91)87115-R

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From comparison of the absorption and MCD spectra of a hetero-dimer complex, naphthalocyaninatophthalocyaninatolutetium(III) ([Lu(Nc)(Pc)], with the corresponding spectra of [Lu(Pc)2] and [Lu(Nc)2] (Pc = phthalocyanine, Nc = naphthalocyanine), the delocalization of the unpaired electron in [Lu(Nc)(Pc)] is demonstrated. The lowest excitations of the hetero-dimer arise in the middle of those of [Lu(Pc)2] and [Lu(Nc)2]. The lowest excited states of these complexes are assigned on the basis of the hole delocalization.

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页码：51 / 56

页数：6

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