STRUCTURE OF THE PRIMARY ADDUCT OF A PHOSPHORUS YLIDE AND FLUORENONE

被引：58

作者：

BESTMANN, HJ ^{[1
]}

ROTH, K ^{[1
]}

WILHELM, E ^{[1
]}

BOHME, R ^{[1
]}

BURZLAFF, H ^{[1
]}

机构：

[1] UNIV ERLANGEN NURNBERG,INST ANGEWANDTE PHYS KRISTALLOG,D-8520 ERLANGEN,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1002/anie.197908761

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The postulated ligand shift process (3) → (4) in the Wittig reaction is proved indirectly by the structure and behavior of the primary adduct from a cyclic phosphorus ylide and fluorenone. This primary adduct is too rigid to rearrange to 4. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：876 / 877

页数：2

共 8 条

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BESTMANN, HJ
[J]. PURE AND APPLIED CHEMISTRY, 1979, 51 (03) : 515 - 533
[2] PREPARATION AND REACTIONS OF A CYCLIC PHOSPHA-ALLENE YLIDE
BESTMANN, HJ
ROTH, K
SAALFRANK, RW
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (12): : 877 - 878
[3] BESTMANN HJ, 1977, ANGEW CHEM, V89, P915
[4] BESTMANN HJ, UNPUBLISHED
[5] BESTMANN HJ, 1977, 1ER ACT C INT COMP P, P519
[6] CRYSTAL STRUCTURE OF A WITTIG INTERMEDIATE CONTAINING A 4-MEMBERED RING . 4,4-BIS(TRIFLUOROMETHYL)2,2,2-TRIPHENYL-3-(TRIPHENYLPHOSPHORANYLIDENE)-1,2-OXAPHOSPHETANE
CHIOCCOLA, G
DALY, JJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (03): : 568 - +
[7] MARQUARDING D, 1973, ANGEW CHEM, V85, P99
[8] MARQUARDING D, 1973, ANGEW CHEM INT EDIT, V12, P91

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