POLYMERIZATION OF CARBAZOLYL-CONTAINING EPOXIDES BY ACTIVATED MONOMER MECHANISM

被引：20

作者：

GRAZULEVICIUS, JV

KUBLICKAS, R

机构：

[1] Department of Organic Technology, Kaunas University of Technology, 233028 Kaunas

来源：

EUROPEAN POLYMER JOURNAL | 1991年 / 27卷 / 12期

关键词：

Activated Monomer Mechanism - Carbazolyl-Containing Epoxide Polymerization - Carbazolyl-Containing Oligoethers - Dibromocarbazolyl-Containing Oligomers - Organic Photoconductors;

D O I：

10.1016/0014-3057(91)90244-I

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Cationic polymerization of 3,6-dibromo-9-(2,3-epoxypropyl)carbazole and 9-(2,3-epoxypropyl)carbazole in the presence of hydroxyl-containing compounds has been studied. It has been established that, at a high enough ratio of the concentrations of a hydroxyl-containing compound and monomer, polymerization occurs by an activated monomer mechanism. Linear increase of molecular weight of polymerization products with conversion and hydroxyl functionality of ca 2 in the obtained oligomer are characteristic features of activated monomer polymerization observed in this work. Carbazolyl-containing oligomers of comparatively wide range of molecular weight and glass transition temperature were obtained. The low glass transition of the oligomers is explained by the presence of a flexible oxyalkylene fragment into the backbone of the oligomer as well as by the orderly distribution of elementary units in the main chain.

引用

页码：1411 / 1416

页数：6

共 12 条

[1] KINETICS OF POLYMERIZATION BY ACTIVATED MONOMER MECHANISM [J].

BIEDRON, T ;

SZYMANSKI, R ;

KUBISA, P ;

PENCZEK, S .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 32 :155-168

[2]

BRUZGA P, IN PRESS POLYM B

[3]

EASTHAM AM, 1966, CHEM CATIONIC POLYM

[4]

GRAZULEVICIUS JV, IN PRESS MAKROMOLEK

[5]

JEDLINSKI ZJ, ACS SYM SER, V187, P205

[6] ACTIVATED MONOMER MECHANISM IN THE CATIONIC POLYMERIZATION OF CYCLIC ETHERS [J].

KUBISA, P .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1988, 13-4 :203-210

[7]

OKAMOTO Y, 1985, ACS SYM SER, V187, P361

[8]

PAUL M, 1964, Patent No. 173797

[9] ACTIVATED MONOMER PROPAGATION IN CATIONIC POLYMERIZATIONS [J].

PENCZEK, S ;

KUBISA, P ;

SZYMANSKI, R .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1986, 3 :203-220

[10]

UNDZENAS A, 1983, Patent No. 1027684

← 1 2 →