Intersystem crossing in methylene

被引：11

作者：

Eder, Thomas W. ^{[1
]}

Carr, Robert W., Jr. ^{[1
]}

Koenst, John W. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem Engn, Minneapolis, MN 55455 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 07期

关键词：

D O I：

10.1016/0009-2614(69)85049-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate of singlet-triplet intersystem crossiug in methylene is a second-order process requiring collisional perturbation to couple with the triplet manifold so that the transition can occur. The efficiency of the process increases with increasing mass of the collision partner, but nevertheless is relatively slow, requiring in excess of 200 gas-kinetic collisions on the average.

引用

页码：520 / 522

页数：3

共 15 条

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