XPS STUDIES OF DAMAGE INDUCED BY X-RAY-IRRADIATION ON CEO2 SURFACES

被引:136
作者
PAPARAZZO, E
机构
[1] Istituto di Struttura della Materia, CNR, 00044 Frascati
关键词
D O I
10.1016/0039-6028(90)90658-U
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Core-level photoemission spectra show that CeO2 is partially reduced to Ce2O3-like phases after prolonged AlKα X-ray exposures. It is suggested that the damage is a result of a locally intense heating of the first few layers of ceria. Experimental evidence is given that some of the Ce 3d XPS features, commonly ascribed in the literature to excited electronic states of CeO2, are actually X-ray induced damage peaks. © 1990.
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页码:L253 / L258
页数:6
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