FACILE PREPARATION AND CHARGE-TRANSFER COMPLEXES OF NAPHTHO[1,8-BC/4,5-B'C']DITHIOPHENE AND 2,5-DIMETHYL AND BIS(METHYLTHIO) DERIVATIVES

被引：15

作者：

TAKIMIYA, K ^{[1
]}

YASHIKI, F ^{[1
]}

ASO, Y ^{[1
]}

OTSUBO, T ^{[1
]}

OGURA, F ^{[1
]}

机构：

[1] HIROSHIMA UNIV, FAC ENGN, DEPT APPL CHEM, HIGASHI KU, HIROSHIMA 724, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 02期

关键词：

D O I：

10.1246/cl.1993.365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Naphtho[1,8-bc:4,5-b'c']dithiophene was conveniently prepared via annulation of benzo[1,2-b:4,3-b']dithiophene and converted to 2,5-dimethyl and bis(methylthio) derivatives. The parent and methylthio compounds have a herringbone type of crystal structures, and formed conductive charge-transfer complexes with iodine and with DDQ.

引用

页码：365 / 368

页数：4

共 5 条

[1]

Allmann R., 1970, Z KRISTALLOGR, V132, P129

[2] PHOTOCHEMICALLY INDUCED CYCLIZATION OF SOME FURYL- AND THIENYLETHENES [J].