APPLICATIONS OF THE BAYLIS-HILLMAN REACTION-2 - A SIMPLE STEREOSELECTIVE SYNTHESIS OF (E)-TRISUBSTITUTED AND (Z)-TRISUBSTITUTED ALKENES

被引：73

作者：

BASAVAIAH, D

SARMA, PKS

BHAVANI, AKD

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期

关键词：

D O I：

10.1039/c39940001091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Grignard reagents with methyl 3-acetoxy-2-methylenealkanoates produces (2E)-2-substituted alk-2-enoates, whereas a similar reaction with 3-acetoxy-2-methylenealkanenitriles provides (2Z)-2-substituted alk-2-enenitriles in high (Z)-stereoselectivity.

引用

页码：1091 / 1092

页数：2

共 21 条

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